By Frederick R. Eirich

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Eng. Data 7, 311 (1962). (g) By correlation. (h) C. B. Hurd, J. Am. Chem. Soc. 68, 364 (1946). (i) J. C. Osthoff and W. T, Grubb, J. Am. Chem. Soc. 76, 399 (1954); D. F. Wilcock, ibid. 68, 691 (1946). (j) A. C. Chapman et ai, J. Chem. Soc. 1960, 3608. varies more slowly than ~m. Hence, their acceptable representation by η ~ m1/2 is understandable. Whether this description is more valid than the "drag effect," suggested earlier with the reference to the phosphazene and siloxane rings, could be tested by isotope substitution effects.

Fink et ai, J. Am. Chem. Soc. 78, 5469 (1956). (d) M. P. " Texaco, New York, 1943. (e)G. Egloff, "Physical Properties of Hydrocarbons," Vol. II. Reinhold, New York, (f ) M. N. , J. Chem. Eng. Data 7, 311 (1962). (g) By correlation. (h) C. B. Hurd, J. Am. Chem. Soc. 68, 364 (1946). (i) J. C. Osthoff and W. T, Grubb, J. Am. Chem. Soc. 76, 399 (1954); D. F. Wilcock, ibid. 68, 691 (1946). (j) A. C. Chapman et ai, J. Chem. Soc. 1960, 3608. varies more slowly than ~m. Hence, their acceptable representation by η ~ m1/2 is understandable.

80, 251 (1949). 46 A. BONDI oxygens. The method of counting segments in polyphenyl ethers is so different from that used for polymethylene that a direct comparison is not possible. One polyether, poly(dimethylsiloxane), cannot be compared at all. Oligomers up to the hexamer (the size limit for good data) behave reasonably like the corresponding alkanes, as shown by the data in Fig. 27d. 55, dB/dT « 0. FIG. 27C. Generalized viscosity vs. temperature curves of various polyphenylethers. From data by C.

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