By Harry B. Gray

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Opt. Soc. , 47, 1076 (1957). 614 eV. '! : The variation of the ionization potential of ato number is shown in Fig. 1-10. I . - 1-17 ELECTRON AFFINITIES . i. 25 - H e first transition series ,; . ,' 0 10 20 30 40 atomic number atomic number. - . Electrons and Chewical Bonding 34 adds an extra electron to give a negative ion. 3p [ A r ] 4 s 23d104p [~r]5s~4d'~5p [ H e ]2 s2 [ N e ] 3sZ [He]2 s [ N e ]3 s [ A r ] 4 s 23d10 [ K r ]5 s2 4 dl0 EA, eV Ovbital electvonic configuvation of AHe Ne Ar Kr Xe [He]2s22 p 5 [ N e ]3 s2 3 p5 [ A r ] 4 s 23 d L 0 4 p 5 [He]2?

I 2 A,, orbitals A, orbitals A , orbitals $' I , U', . '\ 8 ,;, r I I I ' e I 8 / I I (b) Figure 2-15 Molecular-orbital energy-level diagrams for a homonuelear diatomic molecule (a)with no crsn. interaction; (b) with appreciable ususinteraction.

I . - 1-17 ELECTRON AFFINITIES . i. 25 - H e first transition series ,; . ,' 0 10 20 30 40 atomic number atomic number. - . Electrons and Chewical Bonding 34 adds an extra electron to give a negative ion. 3p [ A r ] 4 s 23d104p [~r]5s~4d'~5p [ H e ]2 s2 [ N e ] 3sZ [He]2 s [ N e ]3 s [ A r ] 4 s 23d10 [ K r ]5 s2 4 dl0 EA, eV Ovbital electvonic configuvation of AHe Ne Ar Kr Xe [He]2s22 p 5 [ N e ]3 s2 3 p5 [ A r ] 4 s 23 d L 0 4 p 5 [He]2? 3 p 4 [ ~ r ] 4 s ~ 3 d ~ ~ 4 ~ ~ [ H e 1 2 32 p 3 [ N e ]3 3 p3 [Ar]4s23d104p3 [He]2 ?

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